Wicheeda PFS Floats a 50% TREO Concentrate From 1.8 Mtpa at 55 to 75°C and Refines It by Acid Bake, Water Leach and SX to an NdPr-Rich Carbonate

Defense Metals' 2025 prefeasibility study for the Wicheeda rare earths project near Prince George, British Columbia, pairs a concentrator at the mine with a hydrometallurgical plant at Bear Lake. The refinery produces a mixed rare earth carbonate from which lanthanum and cerium are removed.

The NI 43-101 Technical Report, Wicheeda Rare Earths Project PFS, was prepared by Hatch and other qualified persons for Defense Metals Corp., with an effective date of February 28, 2025 and a report date of April 4, 2025. The concentrator treats 1,800,000 t a year of ore and floats a concentrate grading 50 wt% total rare earth oxides (TREO). The concentrate goes to a hydrometallurgical plant at Bear Lake that makes a high-purity mixed rare earth carbonate (MREC) with an 87 wt% NdPr oxide distribution. The deposit's main lithologies are dolomite carbonatite (66%), xenolite carbonatite (31%) and syenite. The first eight years treat mainly dolomite carbonatite.

Critical Data

Parameter Value Unit Notes
Report effective date February 28, 2025 Not applicable Hatch for Defense Metals Corp.
Ore feed 1,800,000 t/a ROM top size 1,000 mm
Feed grade 2.8 (Years 2 to 8), 1.92 (Years 9 to 15) % TREO Ore SG 2.95
Overall TREO recovery 80.9 (Years 1 to 8), 69.3 (Years 9 to 15) % Forecast
Operating hours Crushing 3,780, milling and flotation 7,728 h/a Filtration 7,140
Grinding Single SAG mill and ball mill, fixed speed Not applicable P80 80 µm
Flotation Rougher, scavenger and two cleaner stages Not applicable 55°C roughing, 75°C cleaning
Concentrate 50% TREO Not applicable Filter cake 7.9% moisture
Hydromet feed 85,800 t/a dry concentrate Not applicable Bear Lake, BC
Acid bake 1,034 kg H2SO4/t, 350°C, 105 min Not applicable Two indirect natural gas kilns
MREC production 10,750 t/a (6,490 t/a TREO) Not applicable 87% NdPr on an REO basis
Tailings Filtered, 9.0% moisture Not applicable Trucked to a filtered tailings facility

Overview

At the mine, ore is jaw crushed and carried by overland conveyor to an enclosed stockpile. It is ground in a SAG-ball circuit and thickened, then floated hot in a rougher, scavenger and two-stage cleaner circuit. Concentrate is thickened, filtered and trucked in half-height containers to the refinery. Tailings are thickened, pumped about 3 km, filtered and trucked to a filtered tailings storage facility. At Bear Lake, the concentrate is mixed with sulphuric acid, baked in rotary kilns and water leached. Thorium, iron, phosphorus and aluminium are removed in two neutralization stages and uranium by ion exchange. Solvent extraction removes lanthanum and cerium, and the remaining rare earths are precipitated with ammonium bicarbonate.

Key Process Stages

Crushing and stockpile. Trucks dump into a ROM bin with a static grizzly and rock breaker. An apron feeder and vibrating grizzly send oversize above 120 mm to the jaw crusher, at 150 mm closed side setting. A self-cleaning magnet removes tramp metal. The enclosed stockpile gives about 24 hours of live feed.

Grinding and thickening. SAG mill discharge passes a trommel to a cyclone cluster closed with the ball mill. Cyclone overflow is trash screened and thickened in a 25 m high-rate thickener with flocculant and coagulant to 50% solids. The thickener and process water tank are covered and insulated to hold 55°C.

Flotation. Four rougher conditioning tanks, the first adjusting pH to 9, feed five rougher cells. Five scavenger cells follow after two more conditioning stages, all at 55°C. Rougher and scavenger concentrates are conditioned in three stages at 75°C and pH 7 with gangue depressants (F220 and Na2SiF6), then cleaned in two stages. Collectors include REEC5, AF3 and Aero 6493, with soda ash as pH modifier.

Concentrate and tailings handling. The concentrate thickener produces 70% solids underflow, and its overflow is held at 75°C. Two filters produce the final cake. Tailings at about 60% solids are pumped about 3 km to a filter plant, and the cake is trucked, placed and compacted.

Acid baking and off-gas. Four pug mills (duty, duty, standby and maintenance) mix the concentrate with 93% sulphuric acid. Acid at 97% could be used if a sulphuric acid plant is co-located. Two kilns bake the paste at 350°C for 105 minutes. Off-gas containing SOx and HF is neutralized with slaked lime, scrubbed and cleaned in a wet electrostatic precipitator. Burner exhaust goes to ammonium bicarbonate regeneration for CO2 capture.

Water leach and purification. The kiln discharge is leached in recirculated gypsum liquor and cooled to 30°C. Primary neutralization with magnesium hydroxide to about pH 2, hydrogen peroxide and ferric sulphate precipitates iron, phosphorus, aluminium and thorium. Secondary neutralization to pH 6 removes the remainder. Strong base anion resin in three columns (lead, lag and one being replaced) removes uranium in single pass.

Solvent extraction and carbonate precipitation. Counter-current mixer-settlers load Y and Pr to Lu onto the organic, leaving La and Ce in the magnesium sulphate raffinate. The rare earths are stripped with dilute sulphuric acid and precipitated as hydrated carbonates with regenerated ammonium bicarbonate. The raffinate goes to magnesium removal with lime.

Additional Interesting Data and Summary

The report identifies the primary neutralization filter cake as the largest predicted loss of Nd and Pr. This is due to incomplete extraction from the concentrate and co-precipitation during neutralization. The off-gas design criteria are approximate and are to be specified further in the next phase.

In summary, the 2025 Wicheeda PFS is a conventional SAG-ball and hot flotation concentrator for a carbonatite rare earth deposit, with a separate sulphuric acid bake refinery. Lanthanum and cerium are removed so that the product carbonate is enriched in NdPr.

Key Processes

  • Jaw crushing and overland conveying
  • SAG and ball milling to P80 80 µm with pre-flotation thickening
  • Heated rougher, scavenger and cleaner flotation of rare earth minerals
  • Concentrate and tailings thickening and filtration
  • Sulphuric acid mixing and rotary kiln baking
  • Water leaching and two-stage neutralization
  • Uranium ion exchange
  • Solvent extraction removal of lanthanum and cerium
  • Ammonium bicarbonate precipitation of mixed rare earth carbonate

Source: NI 43-101 Technical Report, Wicheeda Rare Earths Project PFS, prepared by Hatch and others for Defense Metals Corp., effective date February 28, 2025.

Earlier report summaries

Earlier versions of this profile, based on older technical reports, are retained below for source traceability. Dates and figures reflect each report’s own effective date and are superseded by the current information above.

Wicheeda PEA — 2022 Technical Report

This 2022 preliminary economic assessment outlines the proposed processing route for the Wicheeda rare earth project, comprising a flotation concentrator and a hydrometallurgical plant.

Report context

The Wicheeda project technical report, dated January 2022, describes a preliminary economic assessment (PEA) for a rare earth deposit. Material from the project is envisioned to be processed in a flotation concentrator to produce a rare earth flotation concentrate, which would then be sold into the market for the first four years of operation and subsequently processed in a hydrometallurgical plant to produce a mixed REE precipitate. The report presents conceptual flowsheets and preliminary process design criteria, with metallurgical testwork having been conducted on composites containing about 4.8% TREO.

Processing route

Flotation Concentrator

The proposed concentrator flowsheet will include three-stage crushing, ball mill grinding, rougher and scavenger flotation, and three stages of cleaner flotation at elevated temperature to produce a final flotation concentrate containing 40-50% TREO. The flotation concentrate will be thickened to about 55% solids and then filtered to about 9% moisture. The filtered concentrate will be weighed, sampled and bagged in super-sacks containing 1,000-2,000 kg of concentrate.

Crushing: Run-of-mine material will be hauled to the primary crusher. Primary crushed material will be conveyed to a double-deck secondary screen, with oversize conveyed to a secondary cone crusher. Discharge from the secondary crusher will be conveyed to a tertiary screen, with oversize conveyed to a tertiary cone crusher operating in closed circuit with the tertiary screen. Secondary and tertiary screen undersize (-9.5 mm) will be conveyed to a fine material bin feeding the grinding circuit.

Grinding Circuit: The circuit will consist of a single stage ball mill operating in closed circuit with a cluster of hydrocyclones to produce a final grind size of 80% passing (P80) 106 µm.

Reagent Conditioning and Flotation Circuit: Cyclone overflow from the grinding circuit will be conditioned in a three-stage conditioning circuit with required reagents at 80-85°C. The first stage conditioner will adjust slurry pH to 9.5-10 with soda ash, the second stage will condition with depressants for gangue minerals (F220 and Na2SiF6), and the third stage will condition with mineral collector and activator. The conditioned slurry will advance to rougher flotation. Rougher tailing will be further conditioned before scavenger flotation. Rougher and scavenger concentrates will be combined and conditioned before advancing to three stages of cleaner flotation.

Concentrate Thickening and Filtration: Final flotation concentrate will be thickened in a high-rate thickener to about 55% solids and filtered with a pressure filter to about 9% moisture.

Tailing Thickening: Final flotation tailing will be thickened to about 60% solids in a high-rate thickener and pumped to the tailings storage facility.

Recovery Estimate

Metallurgical test programs on composites containing about 4.8% TREO reported laboratory REO recoveries of 85% into flotation concentrates containing almost 49% TREO. It is noted that actual mined grades will be significantly lower. During the first 10 years of production, plant feed will range from about 2.1% to 3.0% TREO. Due to these lower feed grades, REO recovery has been discounted to 80% into concentrates containing 43% TREO for the first 10 years. For production years 11-16, plant feed grades will decline from about 1.9% to 1.2% TREO, with further discounting applied. The report states that confirmatory testwork on material representing planned mine production grades and mineral content will be required during the next phase of metallurgical testwork.

Hydrometallurgical Plant

The hydrometallurgical plant processes flotation concentrate received as moist filter cake. The flowsheet includes gangue leach, caustic crack, rare earth leach, impurity removal, rare earth precipitation, and HCl regeneration circuits.

Gangue Leach Circuit: Flotation concentrate is received at 290 t/d and passed through surge system into gangue leach tanks with two-hour residence time. Regenerated acid is fed to maintain terminal pH of 3.0 at 50°C. Leached slurry is thickened, pressure filtered, and washed. Filter cake feeds the caustic crack circuit, while pregnant solution is reacted with limestone slurry to pH 5 and sent to Mg-Mn precipitation.

Caustic Crack Circuit: Gangue leach residue is slurried with regenerated 50% NaOH solution at 150°C through agitated tanks providing four hours retention time. Discharge slurry is diluted, cooled, filtered and washed. The filter cake feeds the REE acid leach circuit. The filtrate is reacted with slaked lime in causticization reactors providing six hours residence time. Precipitate is removed and sent to waste; filtrate is evaporated back to 50% NaOH and recirculated.

Rare Earth Leach Circuit: Caustic crack residue is reacted with regenerated HCl at 50°C in reactors providing four hours residence time. Acid maintains terminal free acid of 30 g/L. Leach slurry is treated with H2O2, limestone to pH about 3, and SO4 to precipitate impurities. After filtration, pregnant leach solution is treated with NaHS to remove Pb and Zn. Impurity-free PLS is reacted with high-purity lime to precipitate REE hydrate, which is filtered, washed, partially dried, and placed in FIBC for transport.

HCl Regeneration: CaCl2 solutions from gangue leach and REE leach circuits are combined and agitated with lime slurry to pH 9 to precipitate Mg, Mn, and other metals. Purified CaCl2 solution is evaporated to about 450 g/L CaCl2, cooled and reacted with H2SO4, precipitating CaSO4 and forming 20% HCl solution used in the leach circuits.

Waste Handling: Waste streams are generated in gangue leach, causticization, REE impurity removal, Mg/Mn removal, and CaCl2 conversion. Filter cakes will be blended and transported back to the mine site for combination with flotation tailings.

Key reported parameters

Parameter Units Value Basis
Mine production rate tpy 1,800,000 Design
Mill design capacity tpd 5,000 Design
Life of mine TREO grade % 2.3 Design
Crushing product P80 mm 9.5 Design
Ball mill, feed F80 µm 9,500 Design
Ball mill, product P80 µm 106 Design
Bond ball mill work index (BWI) kWh/t 9.3 Testwork
Abrasion Index, Ai – 0.007 Testwork
Rougher-scavenger flotation temperature °C 80 – 85 Design
Rougher-scavenger flotation pH – 9.5 Design
Cleaner flotation temperature °C 80 – 85 Design
Cleaner flotation pH – 8.5 Design
Flotation retention times scale factor – 2.5 From laboratory testwork
Flotation concentrate grade % TREO 40 – 50 Design target
Concentrate filter cake moisture w/w% 9 Design
Tailings thickener underflow density w/w% 55 Design
Metallurgical testwork composite grade % TREO 4.8 Testwork
Laboratory REO recovery % 85 Testwork
Laboratory concentrate grade % TREO 49 Testwork
Discounted REO recovery (years 1-10) % 80 Design
Discounted concentrate grade (years 1-10) % TREO 43 Design
Hydrometallurgical recover (REE to precipitate) % 87.0 Design
Concentrate tonnage to hydromet plant t/a 100,465 Design
REE content of dried precipitate % TREO 76 Design

Project website: https://www.defensemetals.com/wicheeda-property

Note: Flotation retention times are scaled by a factor of 2.5 from laboratory testwork. Discounted recovery and concentrate grades show adjustments for lower plant feed grades compared to testwork composites.

Technical qualifications

The report states that plant feed grades during the first 10 years of production will range from about 2.1% to 3.0% TREO, compared to metallurgical testwork composites containing about 4.8% TREO. Due to these lower feed grades, REO recovery has been discounted from the 85% laboratory recovery to 80% into concentrates containing 43% TREO for the first 10 years. Plant feed grades will continue to decline during production years 11-16 from about 1.9% to 1.2% TREO, with further discounting applied. The report explicitly states that confirmatory testwork on material representing planned mine production grades and mineral content will be required during the next phase of metallurgical testwork to confirm achievable REO recovery and concentrate grades.

Source: Wicheeda PEA NI 43-101 Technical Report, January 2022, Sections 17 Recovery Methods, 17.1 Flotation Concentrator, 17.1.1 Flotation Concentrator Description, 17.1.2 Recovery Estimate, 17.2 Hydrometallurgical Plant, 17.2.1 Plant Flowsheet and Design Criteria, 17.2.2-17.2.6

Mineral processing basics

Scroll to Top